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285. C. E. Wagner, Q. Wang, A. Melamed, C. R. Fairchild, R. Wild, C. H. Heathcock, "Synthesis and Biological Evaluation of Analogs of Altohyrtin C (Spongistatin 2)," Tetrahedron, 2008, 64, 124-136.

284. H. S. Christie and C. H. Heathcock, "Total Synthesis of (±)-Halichlorine, (±)-Pinnaic Acid, and (±)-Tauropinnaic Acid," Proc. Natl. Acad. Sci. USA, 2004, 101, 12079-12084.

283. M. Brito-Arias, R. Pereda-Miranda and C. H. Heathcock, "Synthesis of Tricolorin F," J. Org. Chem., 2004, 69, 4567-4570. WWW version.

282. C. H. Heathcock, M. McLaughlin, J. Medina, J. L. Hubbs, G. A. Wallace, R. Scott, M. M. Claffey, J. Jayes and G. R. Ott, "Multigram Synthesis of Altohyrtin C (Spongistatin 2), J. Am. Chem. Soc., 2003, 125, 12844-12849. WWW version.

281. Jed L. Hubbs and C. H. Heathcock, "A Second-Generation Synthesis of C1-C28 Portion of the Altohyrtins (Spongistatins)", J. Am. Chem. Soc., 2003, 125, 12836-12843. WWW version.

280. Brant Kedrowski and C. H. Heathcock, "Thiazoline Ring Formation from 2-Methylcysteines and 2-Halomethylalanines", Heterocycles, 2002, 58, 601-634.

279. D. Skyler and C. H. Heathcock, " The Pyridoacridine Family Tree - A Useful Scheme for Designing Synthesis and Predicting Undiscovered Natural Products", J. Natural Products, 2002, 65, 1573-1581. WWW version.

278. J. D. Fell and C. H. Heathcock, "Oxidative Fragmentation of Pregna-14,16-dien-20-ones to 14β-Hydroxyandrost-15-en17-ones", J. Org. Chem., 2001,67, 4742-4746.WWW version.

277. C. M. Blazey and C. H. Heathcock, "Regiochemistry in 1,3-Dipolar Cycloadditions of the Azomethine Ylide Formed Diethyl Aminomalonate and Paraformaldehyde",J. Org. Chem. 2002, 67, 298-300.WWW version.

276. D. Skyler and C. H. Heathcock, "A Simple Biomimetic Synthesis of Styelsamine B", Org. Lett. 2001, 3, 4323-4324.WWW version.

275. M. M. Hinman and C. H. Heathcock, "A Synthetic Approach to the Stemona Alkaloids", J. Org. Chem. 2001, 66, 7751-7756.WWW version.

274. G. A. Wallace and C. H. Heathcock, "Further Studies of the Daphniphyllum Alkaloid Polycyclization Cascade," J. Org. Chem. 2001, 66, 450-454.WWW version.

273. G. A. Wallace, R. W. Scott, and C. H. Heathcock, "Synthesis of the C29-C44 Portion of Spongistatin 1 (Alothyrtin A)," J. Org. Chem. 2000, 65, 4145-4152.WWW version.

272. K. Yamamoto and C. H. Heathcock, "α, β-Epoxy Vinyl Triflates in Pd-Catalyzed Reactions," Org. Lett. 2000, 2, 1709-1712. WWW version.

271. M. A. Toczko and C. H. Heathcock, "Total Synthesis of (±)-Aspidospermidine," J. Org. Chem. 2000, 65, 2642-2645. WWW version.

270. B. Raimundo and C. H. Heathcock, "Synthesis of a Model for C7-C13 of Lankamycin," Org. Lett.2000, 2, 27. WWW version.

269. G. R. Ott and C. H. Heathcock, "A Method for Constructing the C44-C55 Side Chain of Altohyrtin C, Organic Lett. 1999, 1, 1475. WWW version.

268. J. L. Hubbs and C. H. Heathcock, "Total Synthesis of (±)-Isoschizogamine," Org. Lett. , 1999, 1, 1315. WWW version.

267. M. M. Claffey, C. J. Hayes and C. H. Heathcock, "Synthesis of the C1-C28 Portion of Spongistatin 1 (Altohyrtin A)," J. Org. Chem., 1999, 64, 8267. WWW version.

266. J. Fields Liu and C. H. Heathcock, "Total Synthesis of (±)-Cylindridines A and B" J. Org. Chem., 1999, 64, 8263. WWW version.

265. S. Chi and C. H. Heathcock, "Total Synthesis of Preussomerins G and I," Org. Lett. 1999, 1, 1. WWW version.

264. A. K. Mapp and C. H. Heathcock, "Total Synthesis of Myxalamide A," J. Org. Chem. 1999, 64, 23. WWW version.

263. K. M. Aubart and C. H. Heathcock, "A Biomimetic Approach to the Discorhabdin Alkaloids: Total Synthesis of Discorhabdins C and E and Dethiadiscorhabdin D," J. Org. Chem. 1999, 64, 16. WWW version.

262. D. J. Denhart, David A. Griffith and Clayton H. Heathcock, "Synthesis of the Tricyclic Core of Sarain A. Use of Formaldehyde in an Intramolecular Grigg Azomethine Ylid Cyclization," J. Org. Chem. 1998, 63, 9616. WWW version.

261. C. H. Heathcock, R. C. D. Brown and T. C. Norman, "Total Synthesis of Petrosins C and D," J. Org. Chem. 1998, 63, 5013. WWW version.

260. R. W. Scott, J. Epperson and C. H. Heathcock, "Total Synthesis of Petrosin, Petrosin A and Petrosin B," J. Org. Chem. 1998,63, 5001. WWW version.

259. P. W. Crawford, J. Gross, K. Lawson, C. C. Cheng, Q. Dong, F. Liu, Y. L. Luo, B. G. Szczepankiewicz and C. H. Heathcock, "Electrochemical Properties of Some Biologically Active Quinone Derivatives. Furanquinones, Pyridoquinones, and Diplamine, A Cytotoxic Pyridoacridine Alkaloid," J. Electrochemical Soc. 1997 144, 3710.

258. D.P. Larson and C. H. Heathcock, "The Total Synthesis of Tricolorin A," J. Org. Chem. 1997, 62, 8406.WWW version

257. B.G. Szczepankiewicz and C. H. Heathcock, "A Novel Method for Suppression of the Abnormal Fischer Indole Synthesis," Tetrahedron 1997, 26, 8853.

256. C.J. Hayes and C. H. Heathcock, "A Method for Constructing the C18-C28 Dispiroacetal Moiety of Altohyrtin A," J. Org. Chem. 1997, 62, 2678.WWW version

255. R. Parsons and C. H. Heathcock, "Total Synthesis of (-)-Tantazole B Synlett. 1996, 12, 1168.

254. D. Stoermer, S. Caron and C. H. Heathcock, "Total Synthesis of Zaragozic Acid (Squalestatin S1). Degradation to a Relay Compound and Reassembly of the Natural Product," J. Org. Chem. 1996, 61,9115.WWW version

253. S. Caron, D. Stoermer, A. K. Mapp and C. H. Heathcock, "Total Synthesis of Zaragozic Acid (Squalestatin S1). Synthesis of A Relay Compound," J. Org. Chem. 1996, 61, 9126.WWW version

252. K. A. Marshall, A. K. Mapp and C. H. Heathcock, "Synthesis of a 2,7-Dioxatricyclo[4.2.1.0^3,8]nonane; A Model Study for Possible Application in a Synthesis of Dictyoxetane," J. Org. Chem. 1996, 61, 9135.WWW version

251. C. H. Heathcock, "Nature Knows Best; An Amazing Reaction Cascade is Uncovered by Design and Discovery" Proc. Nat. Acad. Sci. 1996, 93, 14323.PDF version

250. M. M. Claffey and C. H. Heathcock, "A Method for Constructing the C2-C12 Dispiroacetal Moiety of Altohyrtin A," J. Org. Chem. 1996, 61, 7646.WWW version

249. R. W. Scott and C. H. Heathcock, "An Efficient Synthesis of 3,4,6-tri-O-benzyl-2-C-methyl-D-glucal," Carbohydrate Research 1996, 291, 205.

248. M.A. Brimble, C. H. Heathcock and G. N. Nobin,"Synthesis and Ene Reactions of Di-(-)-menthyl Diazenedicarboxylate," Tetrahedron: Asymmetry 1996,7, 2007.

247. D. P. Larson and C. H. Heathcock, "Synthesis of the Macrolactone Disaccharide Subunit of Tricolorin A,"J. Org. Chem. 1996, 61, 5208.WWW version

246. C. H. Heathcock, "As We Head Into the 21st Century, is There Still Value in Total Synthesis of Natural Products as a Research Endeavor?," in Chemical Synthesis: Gnosis to Prognosis, eds. C. Chatgilialoglu and V. Snieckus, Kluwwer: Dordrecht, 1996.WWW version

245. S. Caron, A. I. McDonald and C. H. Heathcock, "An Improved Synthesis of 1,6-anhydro-2,3-di-O-benzyl-β -D-xylohexopyranos-4-ulose," J. Carbohydrate Research 1996, 281, 179.

244. T. S. McDermott, A. A. Mortlock and C. H. Heathcock, "Total Syntheses of (-)-Papuamine and (-)-Haliclonadiamine," J. Org. Chem. 1996, 61, 700.WWW version

243. B. C. Raimundo and C. H. Heathcock, "Further Studies on the Anti-Aldol Reaction of Chiral Amides, Synlett 1995, 1213.

242. C. H. Heathcock, M. Clasby, D. A. Griffith, B. R. Henke, and M. J. Sharp, "Progress toward the Synthesis of Sarain A," Synlett 1995, 467. WWW version

241. S. Caron, A. I. McDonald and C. H. Heathcock, "Synthesis of 1-Substituted and 1,4-Disubstituted-2,3-di-O-benzyl-1,6-anhydrogalactofuranoses," J. Org. Chem. 1995, 61, 2780.

240. D. A. Griffith and C. H. Heathcock, "Progress Toward the Synthesis of Sarain A: An Unanticipated Rearrangement," Tetrahedron Letters 1995, 36, 2381.

239. C. H. Heathcock, J. C. Kath, and R. B. Ruggeri, "Daphniphyllum Alkaloids 16. Total Synthesis of (+)-Codaphniphylline," J. Org. Chem. 1995, 60, 1120.

238. C. H. Heathcock and D. Joe, "Daphniphyllum Alkaloids 17. A Possibly Biomimetic Transformation of the Secodaphnane to the Daphnane Skeleton," J.Org. Chem. 1995, 60, 1131.

237. A. V. Vorobjev, M. M. Shakirov, V. A. Raldugin, and C. H. Heathcock "Conformational Analysis of the 10- and 13-Hydroxy Derivatives of Cembrene,"J. Org. Chem. 1995, 60, 63.

236. M. J. Munchhof and C. H. Heathcock, "Total Synthesis of ACRL Toxin IIIb; A Protocol for Parlaying Aldols into Synthons Containing Three Stereocenters Having an [n, n+1, n+4] Relationship," J. Org. Chem. 1994,59, 7566.

235. C. H. Heathcock and S. C. Smith, "Synthesis and Biological Activity of Unsymmetrical Bis-steroidal Pyrazines Related to the Cytotoxic Marine Natural Product Cephalostatin 1," J. Org. Chem. 1994, 59, 6828.

234. R. W. Scott, J. R. Epperson, and C. H. Heathcock, "Total Synthesis of Petrosin," J. Am. Chem. Soc. 1994, 116, 8853.

233. R. L. Parsons, Jr. and C. H. Heathcock, "Total Synthesis of(-)-Thiangazole, a Naturally-Occurring HIV-1 Inhibitor," J. Org. Chem. 1994, 58, 4733.

232. B. G. Szczepankiewicz and C. H. Heathcock, "Total Synthesis of Diplamine, A Strongly Cytotoxic Pyridoacridine Alkaloid from a Pacific Tunicate," J.Org. Chem. 1994, 59, 3512.

231. M. J. Sharp and C. H. Heathcock, "An Unusual Isomerization Under Lawesson Thiation Conditions," Tetrahedron Lett. 1994, 35, 3651.

230. R. L. Parsons, Jr. and C. H. Heathcock, "Revision of the Stereostructure of Mirabazole C," Tetrahedron Lett. 1994, 35, 1379.

229. R. L. Parsons, Jr. and C. H. Heathcock, "Total Synthesis of Mirabazole B,"Tetrahedron Lett. 1994, 35, 1383.

228 A. Ganesan and C. H. Heathcock, "Synthesis of Unsymmetrical Pyrazines by Reaction of 1,4-Diazabutadienes with Enamines, J. Org. Chem. 1993, 58, 6155.

227. D. L. Clark and C. H. Heathcock, "Studies on the Alkylation of Chiral Enolates: Application toward the Total Synthesis of Discodermolide," J. Org.Chem. 1993, 58, 5878.

226. M. A. Brimble and C. H. Heathcock, "Allylic Amination by the Lewis-Acid-Mediated Ene Reaction of Diethyl Azodicarboxylate with Alkenes,J. Org. Chem. 1993, 58, 5261.

225. D. S. Stoermer and C. H. Heathcock, "Total Synthesis of(-)-Alloaristoteline, (-)-Serratoline and (+)-Aristotelone," J. Org.Chem. 1993, 58, 564.

224. N. C. Ihle and C. H. Heathcock, "Palladium-Catalyzed Intramolecular Alkyne-Carbon Monoxide Alkene Insertion Cascade for Synthesis of α-Methylenecyclopentenones," J. Org. Chem. 1993,58, 560.

223. P. D. Theisen and C. H. Heathcock, "Prochiral Recognition in the Reaction of 3-Substituted Glutaric Anhydrides with Chiral Secondary Alcohols," J. Org. Chem. 1993, 58, 142.

222. A. Ganesan and C. H. Heathcock, "A Stereochemical Test of the Mechanism of Electrophilic Substitution in 3-Substituted Indoles," Tetrahedron Lett.1993, 34, 439.

221. B. R. Henke, A. J. Kouklis, and C. H. Heathcock, "The Intramolecular 1,3-Dipolar Cycloaddition of Stabilized Azomethine Ylides to Unactivated Dipolarophiles," J. Org. Chem. 1992, 57, 7056.

220. M. J. Munchhof and C. H. Heathcock, "The Stereochemistry of Enolate Formation in THF-Hexane Mixtures," Tetrahedron Lett. 1992,33, 8005.

219. S. C. Smith and C. H. Heathcock, "A Convenient Procedure for the Synthesis of bis-Steroidal Pyrazines: Models for the Cephalostatins," J. Org.Chem. 1992, 57, 6379.

218. S. K. Thompson and C. H. Heathcock, "Total Synthesis of Some Marasmane and Lactarane Sesquiterpenes," J. Org. Chem. 1992, 57,5979.

217. R. S. C. Lopes, C. Lopes and C. H. Heathcock, "Synthesis of Pancratistatin Models," Tetrahedron Lett. 1992, 33, 6775.

216. M. A. Walker and C. H. Heathcock, "Total Synthesis of (-)-Mirabazole C,"J. Org. Chem. 1992, 57, 5566.

215. C. H. Heathcock, "The Enchanting Alkaloids of Yuzuriha," Angew.Chem. 1992, 104, 675; Angew. Chem. Int. Ed. Engl.1992, 31, 665.

214. S. M. Kerwin and C. H. Heathcock, "Remote Oxidation of Perhydrophenanthrenes by Template-Directed Hydrogen Atom Abstraction," J. Org. Chem. 1992, 57, 4005.

213. C. H. Heathcock, R. B. Ruggeri, and K. F. McClure, "DaphniphyllumAlkaloids. 15. Total Synthesis of (±)-Methyl Homodaphniphyllate and (±)-Daphnilactone A," J. Org. Chem. 1992, 57, 2585.

212. C. H. Heathcock, J. A. Stafford, and D. L. Clark, "DaphniphyllumAlkaloids. 14. Total Synthesis of (±)-Bukittinggine," J. Org. Chem.1992, 57, 2575.

211. C. H. Heathcock and J. A. Stafford, "Daphniphyllum Alkaloids. 13. Total Synthesis of (-)-Secodaphniphylline," J. Org. Chem. 1992,57, 2566.

210. C. H. Heathcock, S. Piettre, R. B. Ruggeri, J. A. Ragan, and J. C. Kath,"Daphniphyllum Alkaloids. 12. A Proposed Biosynthesis of the Pentacyclic Skeleton proto-Daphniphylline, J. Org. Chem. 1992,57, 2554.

209. C. H. Heathcock, M. M. Hansen, R. B. Ruggeri, and J. C. Kath,"Daphniphyllum Alkaloids. 11. Biomimetic Total Synthesis of Methyl Homosecodaphniphyllate. Development of the Tetracyclization Reaction," J. Org. Chem. 1992, 57, 2544.

208. C. H. Heathcock, S. K. Davidsen, Sander Mills, and Mark A. Sanner"Daphniphyllum Alkaloids. 10. Classical Total Synthesis of Methyl Homodaphniphyllate," J. Org. Chem. 1992, 57, 2531.

207. C. H. Heathcock, "Modern Enolate Chemistry: Regio- and Stereoselective Formation of Enolates and the Consequence of Enolate Configuration on Subsequent Reactions," Modern Synthetic Methods, 1992, 6,1.

206. M. A. Walker and C. H. Heathcock, "Extending the Scope of the Evans Asymmetric Aldol Reaction: Preparation of anti and `non-Evans' syn Aldols,"J. Org. Chem. 1991, 56, 5748.

205. C. H. Heathcock, "The Aldol Reaction: Acid and General Base Catalysis," InComprehensive Organic Synthesis, B. M. Trost and I. Fleming, Eds., Pergamon Press: Oxford, 1991.

204. C. H. Heathcock, "The Aldol Reaction: Preformed Group I and Group II Enolates," In Comprehensive Organic Synthesis, B. M. Trost and I.Fleming, Eds., Pergamon Press: Oxford, 1991.

203. N. Van Draanen, S. Arseniyadis, M. T. Crimmins, and C. H. Heathcock, "Protocols for the Preparation of each of the four Possible Stereoisomeric α -Alkyl-β -Hydroxy Carboxylic Acids from a Single Chiral Aldol Reagent," J. Org. Chem. 1991, 56, 2499.

202. C. H. Heathcock, "Understanding and Controlling Diastereofacial Selectivity in Carbon-Carbon Bond-Forming Reactions", Aldrichimica Acta 1990, 23, 99.

201. I. Mori, K. Ishihara, L. A. Flippin, K. Nozaki, H. Yamamoto, P. A. Bartlett, and C. H. Heathcock, "On the Mechanism of Lewis-Acid-Mediated Nucleophilic Substitution Reactions of Acetals," J. Org. Chem.1990, 55, 6107.

200. I. Mori, P. A. Bartlett and C. H. Heathcock, "Stereoselective Additions of Nucleophilic Alkenes to Chiral Thionium Ions," J. Org. Chem.1990, 55, 5966.

199. D. A. Oare and C. H. Heathcock, "Acyclic Stereocontrol in Michael Addition Reactions of Enamines and Enol Ethers," Topics in Stereochemistry, E. L. Eliel and S. H. Wilen, Eds., 1991, 20, 87.

198. J. A. Stafford and C. H. Heathcock, "Asymmetric Total Synthesis of (-)-Secodaphniphylline", J. Org. Chem. 1990, 55, 5433.

197. U.S. PATENT NO. 4,950,775 "Antihypercholesterolemic Compounds and Synthesis Thereof" Inventors: C. H. Heathcock, T. J. Rosen, issued August 21,1990.

196. C. H. Heathcock, S. Piettre, and J. Kath, "Mechanistic Investigations of a Biomimetic Polycyclization Process that leads to the DaphniphyllumAlkaloids," Pure & Applied Chem. 1990, 62, 1911.

195. S. H. Montgomery, M. C. Pirrung, and C. H. Heathcock, "De NovoSynthesis of Carbohydrates by Stereoselective Aldol Reaction: L-Cladinose,"Carbohyd. Res. 1990, 202, 13.

194. S. Piettre and C. H. Heathcock, "Biomimetic Total Synthesis ofProto-Daphniphylline," Science, Washington. D. C. 1990,248, 1532.

193. R. Ruggeri and C. H. Heathcock, "Biomimetic Total Synthesis of (±)-Methyl Homodaphniphyllate," J. Org. Chem. 1990, 55,3714.

192. J. G. Stack, J. J. Doney, R. G. Bergman, and C. H. Heathcock, "Rhenium 2-Oxoalkyl (Enolate) Complexes: Synthesis and Carbon-Carbon Bond Forming Reactions with Nitriles," Organometallics, 1990, 9, 453.

191. S. K. Thompson and C. H. Heathcock, "Effect of Cation, Temperature, and Solvent on the Stereoselectivity of the Horner-Emmons Reaction of Trimethyl Phosphonoacetate with Aldehydes," J. Org. Chem. 1990, 55,3386.

190. S. K. Thompson and C. H. Heathcock, "Total Synthesis of (±)-Isovelleral, a Mutagenic Sesquiterpene Dialdehyde from Lactarius Vellereus," J.Org. Chem. 1990, 55, 3004.

189. J. G. Stack, R. D. Simpson, F. J. Hollander, R. G. Bergman, and C. H. Heathcock, "Carbon-Carbon Bond Forming Reactions of Rhenium Enolates with Terminal Alkenes. Evidence for an Alkyne C-H Oxidative Addition Mechanism, and Observation of Highly Stereoselective Base-Catalyzed Proton Transfer Reactions in Rhenium Metallacycles," J. Am. Chem. Soc. 1990, 112,2716.

188. C. H. Heathcock, M. H. Norman, and D. A. Dickman, "Total Synthesis of (±)-Vallesamidine," J. Org. Chem. 1990, 55, 798.

187. I. Mori, K. Ishihara, and C. H. Heathcock, "New Stereoselective Propanal/Propanoic Acid Synthons for Aldol Reactions," J. Org. Chem.1990 55, 1114.

186. E. R. Burkhardt, R. G. Bergman, and C. H. Heathcock, "Synthesis and Reactions of Nickel and Palladium Carbon-Bound Enolate Complexes,"Organometallics 1990,9, 30.

185. H. Danda, M. M. Hansen, and C. H. Heathcock, "Reversal of Stereochemistry in the Aldol Reactions of a Chiral Boron Enolate," J. Org. Che m.1990, 55, 173.

184. D. A. Oare and C. H. Heathcock, "Stereochemistry of the Michael Addition of Ester and Ketone Enolates to α ,β -Unsaturated Ketones," J. Org. Chem. 1990, 55, 157.

183. D. A. Oare, M. A. Henderson, M. A. Sanner, and C. H. Heathcock, "The Stereochemistry of the Michael Addition of N,N-Disubstituted Amide and Thioamide Enolates to α ,β -Unsaturated Ketones," J. Org.Chem. 1990,55, 132.

182. C. H. Heathcock, D. A. Dickman, and M. H. Norman, "An Approach to the Total Synthesis of (3H)-Indoline Alkaloids," in Proceedings of the First Chulabhorn Science Congress 1987-International Congress of Natural Procucts, Volume III, H. R. H. Chulabhorn Mahidol, Ed., Chulabhorn Foundation: Bangkok, 1989.

181. D. A. Oare and C. H. Heathcock, "Stereochemistry of the Michael Reaction,"Topics in Stereochemistry, E. L. Eliel and S. H. Wilen, Eds.,1989, 19, 227.

180. K. Ishihara, H. Yamamoto, and C. H. Heathcock, "Diastereoselective Aldol Synthesis using Acetal Templates," Tetrahedron Lett. 1989,30, 1825.

179. C. H. Heathcock, T. A. Blumenkopf, and K. M. Smith, "Total Synthesis of (±)-Fawcettimine," J. Org. Chem. 1989, 54, 1548.

178. R. B. Ruggeri, K. F. McClure, and C. H. Heathcock, "Total Synthesis of (±)-Daphnilactone A: A Novel Fragmentation Reaction," J. Am. Chem. Soc. 1989, 111, 1530.

177. D. A. Dickman and C. H. Heathcock "Total Synthesis of (±)-Vallesamidine," J. Am. Chem. Soc. 1989, 111, 1528.

176. G. A. Slough, R. G. Bergman, and C. H. Heathcock, "Synthesis of η ¹-Oxygen-Bound Rhodium Enolates. Applications to Catalytic Aldol Chemistry," J. Am. Chem. Soc. 1989, 111, 938.

175. R. B. Ruggeri and C. H. Heathcock, "A Proposal for the Biosynthesis of the Daphniphyllum Alkaloids," Pure & Applied Chem. 1989,61, 289.

174. C. H. Heathcock, B. R. Davis, and C. R. Hadley, "Synthesis and Biological Evaluation of a Monocyclic, Fully Functional Analog of Compactin," J. Med. Chem. 1989, 32, 197.

173. R. B. Ruggeri, M. M. Hansen, and C. H. Heathcock, "Total Synthesis ofMethyl (±)-Homosecodaphniphyllate: A Highly Efficient Tetracyclization Reaction," J. Am. Chem. Soc. 1988, 110, 8734.

172. M. A. Henderson and C. H. Heathcock, "Acyclic Stereoselection. 44. Diastereoselectivity in the Orthoester Claisen Rearrangement of Chiral Propargylic Alcohols. Use of β -Allenic Esters as Chiral Methylmalonaldehyde Synthons," J. Org. Chem. 1988, 53,4736.

171. S. Hoagland, Y. Morita, D. L. Bai, H.-P. Märki, K. Kees, L. Brown,and C. H. Heathcock, "Acyclic Stereoselection. 43. Stereoselective Synthesis of the C-8 to C-15 Moiety of Erythronolide A," J. Org. Chem.1988, 53, 4730.

170. M. H. Norman and C. H. Heathcock, "An Improved Synthesis of N-Benzyl-5-ethyl-1,2,3,4-tetrahydropyridine," J. Org. Chem. 1988,53, 3370.

169. P. D. Theisen and C. H. Heathcock, "Improved Procedure for Preparation of Optically-Active 3-Hydroxyglutarate Monoesters and 3-Hydroxy-5-oxoalkanoic Acids," J. Org. Chem. 1988, 53, 2374.

168. C. H. Heathcock, B. L. Finkelstein, E. T. Jarvi, P. A. Radel, and C. R.Hadley, "1,4- and 1,5-Stereoselection by Sequential Aldol Addition to α ,β -Unsaturated Aldehydes followed by Claisen Rearrangement. Application to the Total Synthesis of the Vitamin-E Side Chain and the Archaebacterial C40Diol,"J. Org. Chem. 1988, 53, 1922.

167. E. R. Burkhardt, J. J. Doney, G. A. Slough, J. M. Stack, C. H. Heathcock,and R. G. Bergman, "Carbon-Carbon Bond Forming Reactions of Organotransition Metal Enolate Complexes," Pure & Applied Chem. 1988,60, 1.

166. C. H. Heathcock, Ed., Organic Syntheses, Vol. 68, 1988, John Wiley: New York.

165. R. B. Ruggeri and C. H. Heathcock, "Synthesis of Polycyclic Lactam and Lactone Ethers by Intramolecular Reformatsky Reactions. A Model for Construction of the Daphnilactone A Ring System," J. Org. Chem.1987, 52, 5745.

164. I. Mori, P. A. Bartlett, and C. H. Heathcock, "High Diastereofacial Selectivity in Nucleophilic Additions to Chiral Thionium Ions," J. Am. Chem.Soc. 1987, 109, 7199.

163. C. H. Heathcock, C. R. Hadley, T. Rosen, P. D. Theisen, and S. J. Hecker, "Total Synthesis and Biological Evaluation of Structural Analogs of Compactin and Dihydromevinolin," J. Med. Chem. 1987, 30, 1858.

162. M. M. Hansen, P. A. Bartlett, and C. H. Heathcock, "Preparation and Reactions of an Alkylzinc Enolate," Organometallics 1987,6, 2069.

161. E. R. Burkhardt, J. J. Doney, J. G. Stack, C. H. Heathcock, and R. G.Bergman, "Formation of Carbon-Carbon Bonds Using Organotransition Metal Enolate Complexes," J. Mol. Catalysis 1987, 41, 41.

160. E. P. Lodge and C. H. Heathcock, "Steric Effects, as Well as σ *-Orbital Energies, are Important in Diastereoface Differentiation in Additions to Chiral Aldehydes," J. Am. Chem. Soc. 1987, 109, 3353.

159. E. P. Lodge and C. H. Heathcock, "On The Origin of Diastereofacial Selectivity in Additions to Chiral Aldehydes and Ketones: Trajectory Analysis,"J. Am. Chem. Soc. 1987, 109, 2819.

158. S. M. Kerwin, A. G. Paul, and C. H. Heathcock, "Quassinoid Synthesis. 2. Preparation of a Tetracyclic Intermediate Having the Bruceantin Tetrahydrofuran Ring," J. Org. Chem. 1987, 52, 1686.

157. E. R. Burkhardt, J. J. Doney, R. G. Bergman, and C. H. Heathcock,"Tungsten and Molybdenum 2-oxallyl (η ¹-(C)-Enolate) Complexes: Functional Group Transformations, Photochemical Aldol Reactions, and Alkyne/CO Migratory Insertion Reactions," J. Am. Chem. Soc. 1987,109, 2022.

156. M. H. Norman and C. H. Heathcock, "Novel Transformations Leading to 3-Benzylindolizidin-2-ones," J. Org. Chem. 1987, 52,226.

155. C. H. Heathcock and T. W. von Geldern, "Total Synthesis of Norsecurinine," Heterocycles 1987, 25, 75.

154. D. A. Oare and C. H. Heathcock, "Influence of Enolate Geometry on the Stereochemistry of Michael Additions to Ketone Enolates to α ,β -Unsaturated Ketones," Tetrahedron Lett. 1986, 27, 6169.

153. C. H. Heathcock and P. A. Radel, "Total Synthesis of a Slightly Unnatural Product: Confirmation of the Stereostructure of the Archaebacterial C40 Diol by Synthesis of a Stereoisomer," J. Org. Chem. 1986, 51,4323.

152. C. H. Heathcock, S. K. Davidsen, S. Mills, and M. A. Sanner, "Total Synthesis of Methyl Homodaphniphyllate," J. Am. Chem. Soc. 1986,108, 5650.

151. C. H. Heathcock, K. M. Smith, and T. A. Blumenkopf, "Total Synthesis of (±)-Fawcettimine (Burnell's Base A)," J. Am Chem. Soc. 1986,108, 5022.

150. C. H. Heathcock, S. K. Davidsen, K. T. Hug, and L. A. Flippin, "Acyclic Stereoselection. 36. Simple Diastereoselection in the Lewis Acid Mediated Reactions of Enolsilanes with Aldehydes," J. Org. Chem. 1986,51, 3027.

149. S. J. Hecker and C. H. Heathcock, "Total Synthesis of(+)-Dihydromevinolin," J. Am. Chem. Soc. 1986, 108,4586.

148. C. H. Heathcock and S. Arseniyadis, "Acyclic Stereoselection. 35. Effect of Cation on Diastereofacial Selectivity in Aldol Reactions of a Chiral α -Silyloxy Ketone," Tetrahedron Lett. 1985, 26,6009.

147. C. H. Heathcock and D. E. Uehling, "Stereoselection in the Michael Addition Reaction. 4. Diastereofacial Preferences in Lewis Acid Mediated Additions of Enolsilanes to Chiral Enones," J. Org. Chem. 1986,51, 279.

146. A. Streitwieser, Jr. and C. H. Heathcock, Introduction to Organic Chemistry, 3rd Edition, MacMillan Publishing Co., Inc., 1985.

145. S. K. Davidsen and C. H. Heathcock, "A Convenient Method for the Preparation of Bicyclo[3.3.0]oct-1-en-3-one," Synthesis 1986,842.

144. C. H. Heathcock, J. J. Doney, and R. G. Bergman, "The Synthesis and Carbon-Carbon Bond-Forming Reactions of Tungsten, Molybdenum and Rhenium Enolates, Pure & Applied Chemistry 1985, 57, 1789.

143. T. J. Rosen and C. H. Heathcock, "The Synthesis of Mevinic Acids,"Tetrahedron 1986, 42, 4909.

142. S. J. Hecker and C. H. Heathcock, "An Approach to the Synthesis of Mevinolin Based on Intramolecular Diels-Alder Cycloaddition," J. Org. Chem. 1985, 50, 5159.

141. C. H. Heathcock, B. L. Finkelstein, T. Aoki, and C. D. Poulter, "Stereostructure of the Archaebacterial C40 Diol," Science, Washington, D.C. 1985, 229, 862.

140. K. Takai and C. H. Heathcock, "Acyclic Stereoselection. 32. Synthesis and Characterization of the Diastereomeric (4S)-Pentane-1,2,3,4-Tetraols,"J. Org. Chem. 1985, 50, 3247.

139. C. H. Heathcock and D. A. Oare, "Stereoselection in the Michael Addition Reaction. 3. The Relationship Between Ester Enolate Geometry and Adduct Stereochemistry in the Kinetic Michael Reaction of Lithium Enolates with Enones," J. Org. Chem. 1985, 50, 3022.

138. C. H. Heathcock, M. A. Henderson, D. A. Oare, and M. A. Sanner, "Stereoselection in the Michael Addition Reaction. 2. Stereochemistry of the Kinetic Michael Reaction of Amide Enolates with Enones," J. Org. Chem.1985, 50, 3019.

137. P. J. Connolly and C. H. Heathcock, "An Approach to the Total Synthesis of Dendrobine," J. Org. Chem. 1985, 50, 4135.

136. Jeffrey J. Doney, R. G. Bergman, and C. H. Heathcock, "Synthesis, Structure and C-C Bond Forming Reactions of Carbon-Bound Molybdenum, Tungsten and Rhenium Enolates. Detection of an η ³-Oxaallyl Intermediate," J. Am. Chem. Soc. 1985, 107, 3724.

135. C. H. Heathcock, M. H. Norman and D. E. Uehling, "Stereoselection in the Michael Addition Reaction. 1. The Mukaiyama-Michael Reaction," J. Am. Chem.Soc. 1985, 107, 2797.

134. C. H. Heathcock and S. H. Montgomery, "Acyclic Stereoselection. 28. Use of Stereoselective Aldol Methodology in the Total Synthesis of Cladinose,"Tetrahedron Lett. 1985, 26, 1001.

133. T. Rosen and C. H. Heathcock, "Synthetic and Biological Studies of Compactin and Related Compounds. 4. Total Synthesis of (+)-Compactin," J.Am. Chem. Soc. 1985, 107, 3731.

132. S.-I. Kiyooka, H. Sasaoka, R. Fujiyama, and C. H. Heathcock, "Diastereofacial Selectivity in the Lewis Acid Mediated Reactions of Allylsilane with Chiral β -Alkoxy Acetals," Tetrahedron Lett.1984, 25, 5331.

131. C. H. Heathcock, S. D. Young, J. P. Hagen, R. Pilli, and U. Badertscher, "Acyclic Stereoselection. 25. Stereoselective Synthesis of the C-1 to C-7 Moiety of Erythronolide A," J. Org. Chem. 1985, 50,2095.

130. C. H. Heathcock, J. P. Hagen, S. D. Young, R. Pilli, D.-L. Bai, H.-P.Märki, K. Kees, and U. Badertscher, "Simple Diastereoselection in the Formation of α ,β -Dihydroxy Aldehydes: An Aldol Approach to the Synthesis of Erythronolide A," Scripta Chimica 1985, 25,39.

129. T. Rosen, M. J. Taschner, J. A. Thomas, and C. H. Heathcock, "Synthetic and Biological Studies of Compactin and Related Compounds. 3. Synthesis of the Hexalin Portion of Compactin," J. Org. Chem. 1985, 50,1190.

128. C. H. Heathcock, T. W. von Geldern, C. B. Lebrilla, and W. F. Maier, "Nucleophilic Substitution with Inversion of Configuration at the Nucleophile," J. Org. Chem. 1985, 50, 968.

127. C. H. Heathcock, K. T. Hug, and L. A. Flippin, "Acyclic Stereoselection. 27. Simple Diastereoselection in the Lewis Acid Mediated Reactions of Enolsilanes with Benzaldehyde," Tetrahedron Lett. 1984,25, 5793.

126. T. A. Blumenkopf and C. H. Heathcock, "Synthesis of LycopodiumAlkaloids," in Alkaloids: Chemical and Biological Perspectives, Volume 3, S. W. Pelletier, ed., John Wiley & Sons, 1985, 185.

125. C. H. Heathcock, M. C. Pirrung, S. D. Young, J. P. Hagen, E. T. Jarvi, U. Badertscher, H.-P. Märki, and S. Montgomery, "Acyclic Stereoselection. 23. Lactaldehyde Enolate Equivalents," J. Am. Chem. Soc. 1984,106, 8161.

124. T. Rosen, M. J. Taschner, and C. H. Heathcock, "Synthetic and Biological Studies of Compactin and Related Compounds. 2. Synthesis of the Lactone Moiety of Compactin," J. Org. Chem. 1984, 49, 3994.

123. T. Rosen, M. Watanabe, and C. H. Heathcock, "A Convenient Assay for the Optical Purity of Monomethyl 3-Hydroxypentanedioate," J. Org. Chem.1984, 49, 3657.

122. C. H. Heathcock, S.-I. Kiyooka, and T. A. Blumenkopf, "Acyclic Stereoselection. 22. Diastereofacial Selectivity in the Lewis Acid Mediated Reactions of Allylsilanes with Chiral Aldehydes and Enones," J. Org. Chem. 1984, 49, 4214.

121. C. H. Heathcock, C. Mahaim, M. F. Schlecht, and T. Utawanit, "A Synthetic Approach to the Quassinoids," J. Org. Chem. 1984, 49,3264.

120. C. H. Heathcock, E. T. Jarvi, and T. Rosen, "Acyclic Stereoselection. 21. Synthesis of an Ionophore Synthon having Four Asymmetric Carbons by Sequential Aldol Addition, Claisen Rearrangement and Hydroboration," Tetrahedron Lett. 1984, 25, 243.

119. R. A. Bunce, M. F. Schlecht, W. G. Dauben, and C. H. Heathcock, "Organic Reactions at High Pressure. Conjugate Additions of O-Silylated Ketene Acetalsto Activated Enones," Tetrahedron Lett. 1983, 25, 4943.

118. C. H. Heathcock, "The Aldol Addition Reaction," in Asymmetric Synthesis, Volume 3, J. D. Morrison, ed., Academic Press, Inc., New York,1984, 111.

117. C. H. Heathcock, "Stereoselective Aldol Condensations," in Comprehensive Carbanion Chemistry, Volume II, E. Buncel and T. Durst, eds., Elsevier, 1984.

116. S.-I. Kiyooka and C. H. Heathcock, "Acyclic Stereoselection. 20. High Diastereofacial Selectivity in the Stannic Chloride Mediated Reactions of Allylsilanes with Chiral α - and β -Alkoxy Aldehydes, Tetrahedron Lett. 1983, 24, 4765.

115. C. H. Heathcock and J. Lampe, "Acyclic Stereoselection. 17. Simple Diastereoselection in the Addition of Medium- and Long-Chain n-Alkyl Ketone Lithium Enolates to Aldehydes," J. Org. Chem. 1983, 48, 4330.

114. C. H. Heathcock and S. H. Montgomery, "Acyclic Stereoselection. 19. Total Synthesis of (±)-Ristosamine and (±)-Megalosamine," Tetrahedron Lett. 1983, 24, 4637.

113. C. H. Heathcock and B. L. Finkelstein, "1,4-Stereoselection by Sequential Aldol Addition-Claisen Rearrangement. Stereostructure of the C-30 Diol from Messel Shale Kerogen," J. Chem. Soc., Chem. Commun. 1983, 919.

112. C. H. Heathcock, R. A. Jennings, and T. W. von Geldern, "Studies Directed Toward the Total Synthesis of Securinega Alkaloids," J. Org. Chem.1983, 48, 3428.

111. C. H. Heathcock and L. A. Flippin, "Acyclic Stereoselection. 16. High Diastereofacial Selectivity in Lewis Acid Mediated Additions of Enolsilanes to Chiral Aldehydes," J. Am. Chem. Soc. 1983, 105, 1667.

110. T. A. Blumenkopf and C. H. Heathcock, "Stereochemistry of the Sakurai Reaction. Additions to Cyclohexenones and Cycloheptenones," J. Am. Chem. Soc. 1983, 105, 2354 .

109. C. H. Heathcock, S. L. Graham, M. C. Pirrung, F. Plavac, and C. T. White, "Total Synthesis of Sesquiterpenes, 1970-79," in The Total Synthesis of Natural Products, Volume V, ed., J. ApSimon, John Wiley & Sons,1983, 1.

108. C. H. Heathcock, "The Aldol Condensation as a Tool for Stereoselective Organic Synthesis," in Current Trends in Organic Synthesis, H. Nozaki, ed., Pergamon Press, Oxford and New York, 1983, 27.

107. C. H. Heathcock, M. J. Taschner, T. Rosen, J. A. Thomas, C. R. Hadley and G. Popjak, "Synthesis and Biological Activity of the Hexalin Moiety ofCompactin (ML-236B)," Tetrahedron Lett. 1982, 23, 4747.

106. C. H. Heathcock, C. M. Tice, and T. C. Germroth, "Synthesis of Sesquiterpene Antitumor Lactones. 10. Total Synthesis of (±)-Parthenin,"J. Am. Chem. Soc. 1982, 104, 6081.

105. C. H. Heathcock and E. T. Jarvi, "Acyclic Stereoselection. 15. Sequential Aldol-Claisen as a Method for 1,5-Stereoselection. Total Synthesis of the Vitamin-E Side Chain," Tetrahedron Lett. 1982, 23, 2825.

104. C. H. Heathcock, "Acyclic Stereoselection via the Aldol Condensation," ACS Symposium Series, No. 185, Asymmetric Reactions and Processes in Chemistry, E. L. Eliel and S. Otsuka, eds., American Chemical Society, 1982.

103. C. H. Heathcock, E. G. DelMar, and S. L. Graham, "Synthesis of Sesquiterpene Antitumor Lactones. 9. The Hydronaphthalene Route to Pseudoguaianolides. Total Synthesis of (±)-Confertin," J. Am. Chem. Soc. 1982, 104, 1907.

102. C. H. Heathcock, E. F. Kleinman, and E. S. Binkley, "Total Synthesis of Lycopodium Alkaloids: (±)-Lycopodine, (±)-Lycodine and (±)-Lycodoline,"J. Am. Chem. Soc. 1982, 104, 1054.

101. C. H. Heathcock, "Acyclic Stereocontrol Through the Aldol Condensation,Science, Washington, D. C., 1981, 214, 395.

100. C. H. Heathcock, J. P. Hagen, E. T. Jarvi, M. C. Pirrung, and S. D. Young, "Acyclic Stereoselection. 14. O-Alkyllactic Acid Esters: Reagents for the Stereoselective Construction of Erythro- and Threo-Methyl-α ,β -dihydroxy Carbonyl Compounds," J. Am. Chem. Soc. 1981, 103, 4972.

99. C. H. Heathcock, M. C. Pirrung, S. H. Montgomery, and J. Lampe, "Acyclic Stereoselection. 13. Aryl Esters: Reagents for threo-Aldolization,"Tetrahedron 1981, 37, 4087.

98. A. Streitwieser, Jr. and C. H. Heathcock, Introduction to Organic Chemistry, 2nd Edition, MacMillan Publishing Co., Inc., 1981.

97. C. H. Heathcock, M. C. Pirrung, J. Lampe, C. T. Buse, and S. D. Young, "Acyclic Stereoselection. 12. Double Stereodifferentiation with Mutual Kinetic Resolution. A Superior Class of Reagents for Control of Cram's Rule Stereoselection in Synthesis of erythro-α -Alkyl-β -hydroxy Carboxylic Acids from Chiral Aldehydes," J. Org. Chem.1981, 46, 2290.

96. C. H. Heathcock, C. T. White, J. J. Morrison, and D. VanDerveer, "Acyclic Stereoselection. 11. Double Stereodifferentiation as a Method for Achieving Superior Cram's Rule Selectivity in Aldol Condensations with Chiral Aldehydes,"J. Org. Chem. 1981, 46, 1296.

95. D. Schinzer and C. H. Heathcock, "Fluoride-Catalyzed Conversion of Acylsilanes to Aldehydes and Ketones, Tetrahedron Lett. 1981,22, 1881.

94. C. T. White and C. H. Heathcock, "Acyclic Stereoselection. 10. A General Synthesis of erythro-α -Alkyl-β -hydroxy Ketones," J.Org. Chem. 1981, 46, 191.

93. C. H. Heathcock and E. F. Kleinman, "Total Synthesis of (±)-Lycodoline,"J. Am. Chem. Soc. 1981, 103, 222.

92. C. M. Tice and C. H. Heathcock, "Synthesis of Sesquiterpene Antitumor Lactones. 8. An Approach to the Synthesis of Pseudoguaianolides Based on Oxy-Cope Rearrangement," J. Org. Chem. 1981, 46, 9.

91. S. L. Graham and C. H. Heathcock, "Stereoselectivity in the Alkylation of Sulfonium Salts," Tetrahedron Lett. 1980, 3865.

90. J. A. Thomas and C. H. Heathcock, "A Reagent for Cyclohexene Annelation,"Tetrahedron Lett. 1980, 3235.

89. R. W. Dugger and C. H. Heathcock, "An Efficient Preparation oftrans,trans-β -Ionylideneacetaldehyde," Synth. Commun. 1980, 10, 509.

88. C. H. Heathcock, S. D. Young, J. P. Hagen, M. C. Pirrung, C. T. White, and D. VanDerveer, "Acyclic Stereoselection. 9. Stereochemistry of the Addition of Lithium Enolates to α -Alkoxy Aldehydes," J. Org. Chem.1980, 45, 3846.

87. M. C. Pirrung and C. H. Heathcock, "Acyclic Stereoselection. 8. A New Class of Reagents for the Highly Stereoselective Preparation of threo-2-Alkyl-3-hydroxycarboxylic Acids by the Aldol Condensation," J. Org. Chem. 1980, 45, 1727.

86. S. L. Graham and C. H. Heathcock, "The Origin of the Differential Acidity of Diastereotopic Protons in Sulfonium Salts," J. Am. Chem. Soc.1980, 102, 3713.

85. R. W. Dugger and C. H. Heathcock, "A General Synthesis of 5,6-Dihydro-α -pyrones," J. Org. Chem. 1980, 45,1181.

84. C. H. Heathcock, C. T. Buse, W. A. Kleschick, M. C. Pirrung, J. E. Sohn,and J. Lampe, Acyclic Stereoselection. 7. Stereoselective Synthesis of 2-Alkyl-3-hydroxy Carbonyl Compounds by the Aldol Condensation," J. Org.Chem. 1980, 45, 1066.

83. D. Davalian and C. H. Heathcock, "Methyl 13,14-Dihydro-13,14-epoxyretinoate," J. Org. Chem. 1979, 44, 4988.

82. C. H. Heathcock, T. C. Germroth, and S. L. Graham, "Stereochemistry of Cuprate Addition to 4-, 5-, and 6-Alkyl-cycloheptenones," J. Org. Chem.1979, 44, 4481.

81. D. Davalian and C. H. Heathcock, "Synthesis of 7,8-Epoxy-7,8-dihydroretinoids," J. Org. Chem. 1979, 44,4458.

80. C. H. Heathcock, M. C. Pirrung, C. T. Buse, J. P. Hagen, S. D. Young, and J. E. Sohn, "Acyclic Stereoselection. 6. A Reagent for Achieving High1,2-Diastereoselection in the Aldol Conversion of Chiral Aldehydes to 3-Hydroxy-2-methylcarboxylic Acids," J. Am. Chem. Soc. 1979,101, 7077.

79. C. H. Heathcock and C. T. White, "Acyclic Stereoselection. 5. Use of Double Stereodifferentiation to Enhance 1,2-Diastereoselection in Aldol Condensations of Chiral Aldehydes," J. Am. Chem. Soc. 1979,101, 7076.

78. C. H. Heathcock, M. C. Pirrung, and J. E. Sohn, "Acyclic Stereoselection. 4. Assignment of Stereostructure to β -Hydroxycarbonyl Compounds by ¹³C NMR," J. Org. Chem. 1979, 44, 4294.

77. E. Kleinman and C. H. Heathcock, "Total Synthesis of (±)-Lycodine,"Tetrahedron Lett. 1979, 4125.

76. C. H. Heathcock, E. Kleinman, and E. S. Binkley, "Total Synthesis of Lycopodine and Related Alkaloids," rpt. from Stereoselective Synthesis of Natural Products: Proceedings of the Seventh Workshop Conference Hoechst, Schloss Reisenburg, 24-27 September 1978, W. Bartmann and E. Winterfeldt, Eds., Exercpta Medica, Amsterdam-Oxford.

75. D. M. Roush, E. M. Price, L. K. Templeton, D. H. Templeton, and C. H. Heathcock, "Synthesis, Stereostructure, Pyramidal Inversion, and Alkylation of1-Thioniabicyclo[4.4.0]decane Salts," J. Am. Chem. Soc. 1979,101, 2971.

74. F. Plavac and C. H. Heathcock, "Synthesis of Sesquiterpene Antitumor Lactones 7. Studies Directed toward the Total Synthesis of Pentalenolactone. Intramolecular Ene Reaction," Tetrahedron Lett. 1979, 2115.

73. C. H. Heathcock, E. Kleinman, and E. S. Binkley, "A Highly Efficient Total Synthesis of (±)-Lycopodine," J. Am. Chem. Soc. 1978,100, 8036.

72. C. T. Buse and C. H. Heathcock, "Acyclic Stereoselection. 3. Synthesis ofthreo-3-Hydroxy-2-methylcarboxylic Acids," Tetrahedron Lett.1978, 1685.

71. W. A. Kleschick and C. H. Heathcock, "Synthesis and Chemistry of Ethyl 2-Diethylphosphonoacrylate," J. Org. Chem. 1978, 43,1256.

70. C. T. Buse and C. H. Heathcock, "Acyclic Stereoselection. 2. Synthesis of3-Hydroxy-2-methyl- and 3-Hydroxy-2,4-dimethylcarboxylic Acids," J. Am.Chem. Soc. 1977, 99, 8109.

69. D. M. Roush and C. H. Heathcock, "On the Stereostructure of Eastman's Sulfonium Salt. Pyramidal Inversion Barrier of an Unstabilized Sulfonium Ylide," J. Am. Chem. Soc. 1977, 99, 2337.

68. L. G. Kozar, R. D. Clark, and C. H. Heathcock, "Synthesis of Bicyclo-[2.2.2]octenes and Bicyclo[3.2.2]nonenes by π -Cyclization," J. Org.Chem. 1977, 42, 1386.

67. W. A. Kleschick, C. T. Buse, and C. H. Heathcock, "Stereoselection in the Aldol Condensation," J. Am. Chem. Soc. 1977, 99, 247.

66. A Streitwieser, Jr. and C. H. Heathcock, Introduction to Organic Chemistry, MacMillan Publishing Co., Inc., 1976.

65. P. M. Wege, R. D. Clark, and C. H. Heathcock, "Synthesis of Sesquiterpene Antitumor Lactones. 6. cis-8a-Vinyloctahydro-3H-2-benzopyran-3,7-dione, a Precursor to Vernolepin," J. Org. Chem. 1976, 41,3144.

64. J. E. Ellis, J. S. Dutcher, and C. H. Heathcock, "Pentacyclic Triterpene Synthesis. 6. Synthesis of a Bicyclic Intermediate Corresponding to Rings D and E of β -Amyrin," J. Org. Chem. 1976, 41, 2670.

63. J. S. Dutcher, J. G. MacMillan, and C. H. Heathcock, "Pentacyclic Triterpene Synthesis. 5. Synthesis of Optically Pure Ring AB Precursors," J. Org. Chem. 1976, 41, 2663.

62. C. G. Chavdarian, S. L. Woo, R. D. Clark, and C. H. Heathcock, "Synthesis of Sesquiterpene Antitumor Lactones. V. A Model for Rings B and C of Vernolepin," Tetrahedron Lett. 1976, 1769.

61. C. G. Chavdarian and C. H. Heathcock, "Synthesis of Sesquiterpene Antitumor Lactones. IV. A Stereoselective Synthesis oftrans-2,3-Epoxycyclohexanol," Synth. Commun. 1976,6, 277.

60. R. D. Clark and C. H. Heathcock, "Synthesis of a Cytotoxic Vernolepin Prototype. Ozonization of Silyoxyalkenes," J. Org. Chem. 1976,41, 1396.

59. R. D. Clark and C. H. Heathcock, "Preparation and Reactions of β -Chloro-α ,β -unsaturated Ketones," J. Org. Chem.1976, 41, 636.

58. C. G. Chavdarian and C. H. Heathcock, "Synthesis of δ -Lactones from Cyclohexenones. Preparation of a Vernolepin Analog," J. Org. Chem.1975, 40, 2970.

57. R. D. Clark, L. G. Kozar, and C. H. Heathcock, "Alkylation of Diethyl 2-Oxoalkanephosphonates," Synthesis 1975, 635.

56. D. N. Brattesani and C. H. Heathcock, "A Synthetic Approach to the Dendrobine Skeleton," J. Org. Chem. 1975, 40, 2165.

55. E. S. Binkley and C. H. Heathcock, "The Mass Spectra of Some 2,3,5-Trialkylcyclohexanones," J. Org. Chem. 1975, 40,2160.

54. E. S. Binkley and C. H. Heathcock, "Regiospecific Alkylation of Enolate Ions in Liquid Ammonia-Tetrahydrofuran," J. Org. Chem. 1975,40, 2156.

53. C. G. Chavdarian and C. H. Heathcock, "Preparation and Synthetic Applications of Lithium Di(α -methoxy-vinyl)cuprate," J. Am. Chem.Soc. 1975, 97, 3822.

52. R. D. Clark and C. H. Heathcock, "Synthesis of Spiro Lactones and Ketonesvia Conjugate Addition to Cyclopropyl Malonates and β -Keto Esters," Tetrahedron Lett. 1975, 529.

51. R. D. Clark, L. G. Kozar, and C. H. Heathcock, "Cyclopentenones from β ,ε -Diketo Phosphonates. Synthesis of cis-Jasmone,"Synth. Commun. 1975, 5, 1.

50. D. N. Brattesani and C. H. Heathcock, "Sulfenylation and Selenylation of Nitriles," Tetrahedron Lett. 1974, 2279.

49. R. D. Clark and C. H. Heathcock, "Ozonization of Silyloxyalkenes,"Tetrahedron Lett. 1974, 2027.

48. R. D. Clark and C. H. Heathcock, "A New Synthesis of the Vernolepin A-Ring," Tetrahedron Lett. 1974, 1713.

47. J. E. Ellis, J. S. Dutcher, and C. H. Heathcock, "Pentacyclic Triterpene Synthesis. IV. A New Method for Accomplishing Robinson-Nazarov Annelations,"Synth. Commun. 1974, 4, 71.

46. J. S. Dutcher and C. H. Heathcock, "Pentacyclic Triterpene Synthesis. III. Preparation of an Optically Active Synthon for Rings A and B," Tetrahedron Lett. 1974, 933.

45. J. S. Dutcher, J. G. MacMillan, and C. H. Heathcock, "Pentacyclic Triterpene Synthesis. II. Preparation of an AB Synthon," TetrahedronLett. 1974, 929.

44. R. D. Clark and C. H. Heathcock, "A New Procedure for the Preparation of β -Chloro-α ,β -unsaturated Ketones," Synthesis1974, 47.

43. C. H. Heathcock, "Total Synthesis of Sesquiterpenes," in The Total Synthesis of Natural Products, Volume II, edited by John ApSimon, John Wiley & Sons, 1973, 197.

42. R. D. Clark, J. E. Ellis, and C. H. Heathcock, "Methylation of Dimedone,"Synth. Commun. 1973, 3, 347.

41. R. D. Clark and C. H. Heathcock, "The Reduction of β -Halo-α ,β -unsaturated Ketones," J. Org. Chem.1973, 38, 3658.

40. D. N. Brattesani and C. H. Heathcock, "A Convenient Procedure for the Alkylation of Acetylenes," Synth. Commun. 1973, 3, 245.

39. C. H. Heathcock, R. Ratcliffe, and J. Van, "Synthesis of Hydroazulenes by Solvolytic Rearrangement of 9-Methyl-1-decalyl Tosylates," J. Org. Chem. 1972, 37, 1796.

38 B. E. Ratcliffe and C. H. Heathcock, "Synthesis and Characterization of 8-Methylspiro[4.5]dec-7-en-6-one and 6-Methylspiro[4.5]dec-6-en-8-one,"Synth. Commun. 1972, 2, 157.

37. Y. Amano and C. H. Heathcock, "(±)-Occidentalol: Absolute Stereostructure and Total Synthesis," Can. J. Chem. 1972,50, 340.

36. C. H. Heathcock and B. E. Ratcliffe, "Acid-Catalyzed Rearrangement of 6-Methyltricyclo[4.4.0.0^2,7]decan-3-one," J. Org. Chem. 1972, 37, 1298.

35. B. E. Ratcliffe and C. H. Heathcock, "Acid-Catalyzed Rearrangement of Tricyclo[4.4.0.0^2,7]decan-3-ols," J. Org. Chem. 1972,37, 531.

34. C. H. Heathcock and R. A. Badger, "Photochemistry of 1,6-Cyclodecadienes. II. Synthesis and Photochemistry of 6-Methyl-1,6-cyclodecadien-3-one," J. Org. Chem. 1972, 37, 234.

33. C. H. Heathcock, R. A. Badger, and R. A. Starkey, "Photochemistry of1,6-Cyclodecadienes. I. 1-Methyl-(E,E)-1,6-cyclodecadiene," J. Org. Chem. 1972, 37, 231.

32. C. H. Heathcock, J. E. Ellis, J. E. McMurry, and A. Coppolino, "Acid-Catalyzed Robinson Annelations," Tetrahedron Lett. 1971,4995.

31. C. H. Heathcock and J. E. Ellis, "Pentacyclic Triterpene Synthesis. Preparation of a Useful Intermediate," Chem. Commun. 1971,1474.

30. C. H. Heathcock and D. Gray, "On Mukharji's Cyclodecadieneone,"Tetrahedron 1971, 27, 1239.

29. C. H. Heathcock and R. Ratcliffe, "A Stereoselective Total Synthesis of the Guaiazulenic Sesquiterpenoids α -Bulnesene and Bulnesol," J. Am. Chem. Soc. 1971, 93, 1746.

28. A. Hassner, R. P. Hoblitt, C. H. Heathcock, J. E. Kropp, and M. Lorber, "Electronic vs. Steric Effects in the Addition of Iodine Isocyanate to Olefins," J. Am. Chem. Soc. 1970, 92, 1326.

27. C. H. Heathcock and S. R. Poulter, "Catalytic Hydrogenation of Cyclopropyl Alkenes. III. On the Mechanism of Homogeneous Hydrogenation in the Presence of Tris(triphenylphosphine)chlororhodium(I)," Tetrahedron Lett. 1969, 2755.

26. C. H. Heathcock, "A New Synthesis of Alkyl Azides," Angew. Chem., Internat. Edit. Engl. 1969, 8, 134.

25. C. H. Heathcock, L. G. Gulick and T. Dehlinger, "Reaction of Furyllithium with Carboxylic Acids" J. Heterocyclic Chem. 1969, 6,141.

24. C. H. Heathcock, J. E. Ellis, and R. A. Badger, "Reaction of Alkyllithium Reagents with 2,2-Dialkyl-1,3-dioxolanes," J. Heterocyclic Chem. 1969, 6, 139.

23. C. H. Heathcock and R. A. Badger, "Synthesis and Photocyclization of a Cyclododecadienone," Chem. Commun. 1968, 1510.

22. S. R. Poulter and C. H. Heathcock, "Catalytic Hydrogenation of Cyclopropyl Alkenes. II. Nature of the Intermediates in the Heterogeneous Hydrogenolysis Reaction," Tetrahedron Lett. 1968, 5343.

21. S. R. Poulter and C. H. Heathcock, "Catalytic Hydrogenation of Cyclopropyl Alkenes. I. Effect of the Alkyl Substitution on the Heterogeneous Hydrogenolysis Reaction," Tetrahedron Lett. 1968, 5339.

20. C. H. Heathcock and B. E. Ratcliffe, "An Unusual Cyclobutane Pyrolysis,"J. Org. Chem. 1968, 33, 3650.

19. C. H. Heathcock and R. Ratcliffe, "Formation of Hydroazulenes by Solvolytic Rearrangement of 6-Methyldecalin-1-toluene-p-sulphonates," Chem. Commun., 1968, 994.

18. C. H. Heathcock and S. R. Poulter, "The Effect of Cyclopropyl Substitutionon the π ->π * Transition of Simple Olefins," J. Am. Chem. Soc. 1968, 90, 3766.

17. C. H. Heathcock and Y. Amano, "Sesquiterpenoids. V. The Synthesis and Formolysis of 4aβ ,8β -Dimethyl-8aα -hydroxydecahydronaphth-2β -oic Acid and 4β ,8β -Dimethyl-8α -hydroxydecahydronaphth-2α -oic Acid Lactone," Tetrahedron 1968, 24, 4917.

16. C. H. Heathcock and T. R. Kelly, "Sesquiterpenoids. IV. Acid-Catalyzed Methyl Migration in 9-Methyl Decalins," Tetrahedron 1968, 24, 3753.

15. C. H. Heathcock and T. R. Kelly, "Total Synthesis of Nor-ketoagarofuran,"Chem. Commun. 1968, 267.

14. C. H. Heathcock and T. R. Kelly, "Sesquiterpenoids. III. Total Synthesis of Eudesmane Sesquiterpenoids," Tetrahedron 1968, 24,1801.

13. A. Hassner, M. E. Lorber, and C. H. Heathcock, "Addition of Iodine Isocyanate to Olefins. Scope and Synthetic Utility," J. Org. Chem. 1967, 32, 540.

12. C. H. Heathcock, R. A. Badger, and J. W. Patterson, Jr., "Total Synthesis of (±)-Copaene and (±)-Ylangene. A General Method for Synthesis of Tricyclo[4.4.0.0^2,7]decanes," J. Am. Chem. Soc. 1967, 89, 4133.

11. C. H. Heathcock, "The Total Synthesis of (±)-Copaene and (±)-8-Isocopaene," J. Am. Chem. Soc. 1966, 88, 4110.

10. C. H. Heathcock, "The Synthesis of 1-Methyltricyclo[4.4.0.0^2,7]decanes," Tetrahedron Lett. 1966, 2043.

9. M. J. Jorgenson and C. H. Heathcock, "Photochemistry of Cyclopropylacrylic Esters," J. Am. Chem. Soc. 1965, 87, 5264.

8. A. Hassner and C. H. Heathcock, "Synthesis and Ring Opening of Fused Steroidal Aziridines," J. Org. Chem. 1965, 30, 1748.

7. A. Hassner and C. H. Heathcock, "Synthesis of Fused Ethyleneimines from Cyclic Olefins," Tetrahedron 1964, 20, 1037.

6. A. Hassner and C. H. Heathcock, "Stereospecific Additions to Olefins. The Iodonium Ion," Tetrahedron Lett. 1964, 1125.

5. A. Hassner and C. H. Heathcock, "On the Mechanism of the Conversion of β -Iodo Carbamates to Aziridines," J. Org. Chem. 1964, 29, 3640.

4. A. Hassner and C. H. Heathcock, "Reaction of Nitrosyl Chloride with Steroid-5-Enes. NMR as a Stereochemical Tool in Steroids," J. Org. Chem. 1964, 29, 1350.

3. A. Hassner and C. H. Heathcock, "The Stereochemistry of Ethyleneimines Fused to Six-Membered Rings," Tetrahedron Lett. 1963, 393.

2. A. Hassner and C. H. Heathcock, "Formation of 2-Oxazolidones from β -Iodourethanes. A Stereospecific Synthesis of cis-β -Amino Alcohols," Angew. Chem., Internat. Edit. Engl. 1963, 2, 213.

1. C. H. Heathcock, "The Chemical Shift of Aromatic Alkoxy Groups," Can. J. Chem. 1962, 40, 1865.